(Z)-8-DODECEN-1-YL ACETATE
-
Product Name :
(Z)-8-DODECEN-1-YL ACETATE
-
CAS No :
28079-04-1
-
Project State :
Commercial
Application
General Description
Good factory exports good (Z)-8-DODECEN-1-YL ACETATE 28079-04-1
- Molecular Formula:C14H26O2
- Molecular Weight:226.359
- Vapor Pressure:0.00114mmHg at 25°C
- Refractive Index:1.448
- Boiling Point:300.1 °C at 760 mmHg
- Flash Point:96.5 °C
- PSA：26.30000
- Density:0.881 g/cm3
- LogP:4.24640
(Z)-8-DODECEN-1-YL ACETATE(Cas 28079-04-1) Usage
|
Synthesis Reference(s) |
Tetrahedron Letters, 14, p. 675, 1973 DOI: 10.1016/S0040-4039(00)72431-2 |
|
General Description |
(Z)-8-DODECEN-1-YL ACETATE is a sex pheromone component found in many Lepidoptera species, synthesized via a three-step process from cyclooctene. It is produced by the acetylation of (Z)-8-dodecen-1-ol, which is derived from the reduction of methyl (Z)-8-dodecenoate, itself obtained through ozonolysis and Wittig coupling. (Z)-8-DODECEN-1-YL ACETATE is structurally characterized by a (Z)-configured double bond at the 8-position and an acetate ester at the terminal carbon, playing a key role in insect communication. |
InChI:InChI=1/C14H26O2/c1-3-4-5-6-7-8-9-10-11-12-13-16-14(2)15/h5-6H,3-4,7-13H2,1-2H3/b6-5-
28079-04-1 Relevant articles
PHEROMONES OF INSECTS AND THEIR ANALOGS. XXI. SYNTHESIS OF ALK-8Z-EN-1-OLS AND THEIR ACETATES FROM A FUNCTIONALLY DIFFERENTIATED PRODUCT OF OZONOLYSIS OF CYCLOOCTENE
Odinokov, V. N.,Akhmetova, V. R.,Khasanov, Kh. D.,Abduvakhabov, A. A.,Tolstikov, G. A.,Panasenko, A. A.
, p. 240 - 243 (1989)
Dodec-8Z-en-1-ol (VIII) and tetradec-8Z-...
-
Sonnet,P.E.,Oliver,J.E.
, p. 3284 - 3286 (1976)
-
SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS
-
Paragraph 0261; 0267, (2021/12/28)
Disclosed herein are methods for synthes...
SYNTHESIS OF STRAIGHT-CHAIN LEPIDOPTERAN PHEROMONES THROUGH ONE- OR TWO- CARBON HOMOLOGATION OF FATTY ALKENES
-
, (2020/02/14)
Methods for the preparation of alkenes i...
Synthesis method of (Z/E)-8-dodecen-1-alcohol acetate compound
-
, (2019/05/21)
The invention provides a synthesis metho...
SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS
-
, (2018/09/12)
Methods for preparation of olefins, incl...
28079-04-1 Process route
-
-
153123-34-3
Δ8-dodecen-1-ol
-
-
108-24-7
acetic anhydride
-
-
28079-04-1
(Z)-8-dodecen-1-yl acetate
| Conditions | Yield |
|---|---|
|
With
pyridine;
at 5 - 25 ℃;
for 2h;
Large scale;
|
95% |
-
-
40642-40-8
(Z)-8-dodecenol
-
-
108-24-7
acetic anhydride
-
-
28079-04-1
(Z)-8-dodecen-1-yl acetate
| Conditions | Yield |
|---|---|
|
With
pyridine;
In
dichloromethane;
at 20 ℃;
for 12h;
chemoselective reaction;
Inert atmosphere;
|
90% |
|
With
pyridine;
|
89% |
|
In
pyridine;
for 24h;
Ambient temperature;
|
75% |
|
In
pyridine;
for 4h;
Ambient temperature;
|
|
|
With
pyridine;
at 20 ℃;
for 15h;
Yield given;
|
|
|
With
acetic acid;
at 40 ℃;
|
28079-04-1 Upstream products
-
38363-29-0
(E)-8-dodecenyl acetate
-
40642-40-8
(Z)-8-dodecenol
-
75-36-5
acetyl chloride
-
26906-26-3
1-Acetoxydodec-8-yne