Bisphenoxyethanolfluorene
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Product Name :
Bisphenoxyethanolfluorene
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CAS No :
117344-32-8
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Project State :
Commercial
Application
General Description
Cost-effective and customizable Bisphenoxyethanolfluorene 117344-32-8 in stock
- Molecular Formula:C29H26O4
- Molecular Weight:438.523
- Melting Point:117-120 °C(lit.)
- Boiling Point:610.7 °C at 760 mmHg
- PKA:13.95±0.10(Predicted)
- Flash Point:323.1 °C
- PSA：58.92000
- Density:1.248 g/cm3
- LogP:4.79190
117344-32-8 Relevant articles
Synthesis of fluorenebisphenoxy derivatives by acid-sulfur compound catalyzed condensation reaction
Yamada, Mitsuaki,Sun, Jun,Suda, Yasuhiro,Nakaya, Tadao
, p. 1055 - 1056 (1998)
An efficient method for the synthesis of...
Efficient microwave-assisted synthesis of 9,9-bis[4-(2-hydroxyethoxy) phenyl]fluorene from 9-fluorenone and 2-phenoxyethanol
Hiroki, Kazuaki,Morii, Nahoko,Yamashita, Hiroshi,Sugiyama, Jun-Ichi
, p. 4407 - 4413 (2007)
9-Fluorenone (1) smoothly reacts with ph...
Synthesis method of 9, 9-di [4-(2-hydroxyethoxy) phenyl] fluorene
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Paragraph 0036-0060, (2021/01/15)
The invention discloses a synthesis meth...
A fluorene skeleton fragrant ether class compound preparation method (by machine translation)
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Paragraph 0031-0040; 0049-0052, (2018/12/13)
A fluorene skeleton fragrant ether class...
9,9-BIS(4-(2-HYDROXYETHOXY)PHENYL)FLUORENE CRYSTAL
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Paragraph 0056; 0077; 0084, (2018/04/21)
PROBLEM TO BE SOLVED: To produce 9,9-bis...
9, 9 - bis (4 - (2 - hydroxyethoxy) phenyl) fluorene in production, and the crystal, and production of the crystal
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Paragraph 0024, (2017/07/13)
A method for producing 9,9-bis(4-(2-hydr...
117344-32-8 Process route
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122-99-6,56257-90-0,9004-78-8
2-Phenoxyethanol
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486-25-9,952573-42-1
9-fluorenone
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117344-32-8
9,9-bis(4-(2-hydroxyethoxy)phenyl)fluorene
| Conditions | Yield |
|---|---|
|
With
sulfuric acid; ethanethiol;
for 12h;
Reagent/catalyst;
Reflux;
|
94.5% |
|
With
3-mercaptopropionic acid;
In
chlorobenzene;
at 115 ℃;
for 2h;
Solvent;
Temperature;
Reagent/catalyst;
|
92.5% |
|
tungstophosphoric acid;
In
toluene;
at 130 ℃;
for 4h;
under 15.0015 Torr;
Product distribution / selectivity;
Inert atmosphere;
|
90.2% |
|
With
methanesulfonic acid; 3-(tritylthio) propanoic acid;
at 50 ℃;
for 18h;
Inert atmosphere;
|
85.4% |
|
phosphotungstic acid;
In
toluene;
for 12h;
Product distribution / selectivity;
Inert atmosphere;
Reflux;
|
75.1% |
|
With
sulfuric acid; 3-mercaptopropionic acid;
at 65 ℃;
for 5h;
Mechanism;
further acid catalysts and co-catalysts, further temperatures and reaction time;
|
73.8% |
|
With
sulfuric acid; 3-mercaptopropionic acid;
at 65 ℃;
for 5h;
|
73.8% |
|
With
Al(3+)-montmorillonite; 3-mercaptopropionic acid;
at 160 ℃;
for 0.166667h;
microwave irradiation;
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70% |
|
With
hydrogen fluoride; 3-mercaptopropionic acid;
at -40 - 80 ℃;
for 17h;
Reagent/catalyst;
Temperature;
Autoclave;
Inert atmosphere;
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104.5 g |
|
2-Phenoxyethanol; 9-fluorenone;
In
1,2-dichloro-ethane;
at 40 ℃;
for 2h;
With
3-mercaptopropionic acid;
In
1,2-dichloro-ethane;
at 20 ℃;
for 0.333333h;
|
|
|
2-Phenoxyethanol; 9-fluorenone;
In
1,2-dichloro-ethane;
at 40 ℃;
for 2h;
With
3-mercaptopropionic acid;
In
1,2-dichloro-ethane;
at 20 ℃;
for 0.333333h;
|
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75-21-8,99932-75-9
oxirane
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3236-71-3
9,9-bis(4-hydroxyphenyl)fluorene
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117344-32-8
9,9-bis(4-(2-hydroxyethoxy)phenyl)fluorene
| Conditions | Yield |
|---|---|
|
With
potassium hydroxide;
In
water; isopropyl alcohol;
at 30 - 65 ℃;
for 6.83333h;
Solvent;
Temperature;
Reagent/catalyst;
|
91.5% |
117344-32-8 Upstream products
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122-99-6
2-Phenoxyethanol
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486-25-9
9-fluorenone
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75-21-8
oxirane
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3236-71-3
9,9-bis(4-hydroxyphenyl)fluorene
117344-32-8 Downstream products
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161182-73-6
9,9-bis[4-(2-acryloyloxyethoxy)phenyl]fluorene
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259881-39-5
9,9-bis[4-(2,3-epoxypropoxyethoxy)phenyl]fluorene