Tris(trimethylsilyl) borate
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Product Name :
Tris(trimethylsilyl) borate
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CAS No :
4325-85-3
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Project State :
Commercial
Application
General Description
Manufacturers supply cost-effective and customizable Tris(trimethylsilyl) borate 4325-85-3
- Molecular Formula:C9H27BO3Si3
- Molecular Weight:278.379
- Appearance/Colour:colorless clear liquid
- Vapor Pressure:0.931mmHg at 25°C
- Melting Point:-35 °C
- Refractive Index:n20/D 1.386(lit.)
- Boiling Point:186 °C at 760 mmHg
- Flash Point:42.8 °C
- PSA：27.69000
- Density:0.855 g/cm3
- LogP:3.52580
TRIS(TRIMETHYLSILOXY)BORON(Cas 4325-85-3) Usage
InChI:InChI=1/C9H27BO3Si3/c1-14(2,3)11-10(12-15(4,5)6)13-16(7,8)9/h1-9H3
4325-85-3 Relevant articles
Synthesis of high-purity tris(trimethylsilyl) borate
Voronkov,Basenko,Mirskov,Adamovich
, p. 1721 - 1722 (2006)
A method was developed for synthesis of ...
Catalyseurs pour la transformation de polydimethylsilanes en polycarbosilanes
Duboudin, Francoise,Birot, Marc,Babot, Odile,Dunogues, Jacques,Calas, Raymond
, p. 125 - 132 (1988)
The conversion of polydimethylsilanes in...
A three (three hydrocarbyl silicon-based) borate synthesis method
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Paragraph 0048; 0049, (2019/03/28)
The invention discloses a three-(three h...
Three (trimethyl silicon-based) borate synthesis method
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Paragraph 0016-0017, (2017/08/31)
The invention discloses a synthesis meth...
Preparation of phenylalkyl ethers and phenyl esters from benzenediazonium tetrafluoroborate with alkoxytrimethylsilanes and trimethylsilyl esters
Olah,Wu
, p. 204 - 206 (2007/10/02)
Sonication assisted reaction of benzened...
4325-85-3 Process route
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11113-50-1,14635-83-7
boric acid
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999-97-3
1,1,1,3,3,3-hexamethyl-disilazane
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4325-85-3
tris(trimethylsilyl)borate
| Conditions | Yield |
|---|---|
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With
Amberlyst 15;
at 60 - 65 ℃;
for 1h;
Temperature;
|
86.9% |
|
In
neat (no solvent);
byproducts: NH3; heating (70-85°C, then 110-120°C, several h); distn. (vac.);
|
71.4% |
|
In
neat (no solvent);
byproducts: NH3; addn. of boric acid with agitation to excess of hexamethyldisilazane, refluxing the mixt., until no NH3 is further degassed; distn.;
|
60% |
|
With
zephirol;
at -10 - 130 ℃;
Large scale;
Green chemistry;
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1408 g |
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2754-27-0
trimethylsilyl acetate
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4325-85-3
tris(trimethylsilyl)borate
| Conditions | Yield |
|---|---|
|
With
boric acid;
at 110 ℃;
for 1h;
|
95% |
4325-85-3 Upstream products
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75-77-4
chloro-trimethyl-silane
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1825-62-3
ethyl trimethylsilyl ether
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107-46-0
Hexamethyldisiloxane
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369-57-3
benzenediazonium tetrafluoroborate
4325-85-3 Downstream products
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18306-29-1
bis(trimethylsilyl)sulphate
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11113-50-1
boric acid
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4887-24-5
triacetoxyborane
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17905-96-3
tris(trimethylsilyloxy)boroxine