METHYL TRIFLUOROPYRUVATE
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Product Name :
METHYL TRIFLUOROPYRUVATE
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CAS No :
13089-11-7
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Project State :
Commercial
 
            Application
General Description
Cost-effective and customizable METHYL TRIFLUOROPYRUVATE 13089-11-7 supplier
- Molecular Formula:C4H3F3O3
 - Molecular Weight:156.061
 - Appearance/Colour:clear colorless to light yellow liquid
 - Melting Point:84-86 °C
 - Refractive Index:n20/D 1.332(lit.)
 - Boiling Point:58.5 °C at 760 mmHg
 - Flash Point:80 °F
 - PSA:43.37000
 - Density:1.398 g/cm3
 - LogP:0.29080
 
13089-11-7 Relevant articles
Green synthesis of methyl trifluoropyruvate catalyzed by solid acids
Lermontov, Sergey A.,Ushakova, Lyudmila L.,Kuryleva, Nina V.
, p. 332 - 334 (2008)
Solid acids - NiSO4/Al2O3, Fe2(SO4)3/Al2...
Methyl 3,3,3-trifluoropyruvate: An improved procedure starting from hexafluoropropene-1,2-oxide; identification of byproducts
Dolensky, Bohumil,Kví?ala, Jaroslav,Pale?ek, Ji?í,Paleta, Old?ich
, p. 67 - 74 (2007/10/03)
Optimized laboratory-scale preparation o...
UNUSUAL REACTION CHEMISTRY IN THERMAL DECOMPOSITION OF ALKALI METAL 2-ALKOXY-2,3,3,3-TETRAFLUOROPROPIONATE SALTS
Pellerite, Mark J.
, p. 43 - 66 (2007/10/02)
Pyrolyses of several salts ROCF(CF3)CO2(...
ALKOXYPENTAFLUOROACETONES
Bloshchitsa, F. A.,Burmakov, A. I.,Kunshenko, B. V.,Alekseeva, L. A.,Yugupol'skii, L. M.
, p. 1563 - 1564 (2007/10/02)
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13089-11-7 Process route
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                                         - 
                                        10186-63-7
                                        
2-fluoro-2-methoxy trifluoropropanoic acid methyl ester
 
                                - 
                                        
                                            
                                         - 
                                        13089-11-7
                                        
methyl 3,3,3-trifluoropyruvate
 
                                - 
                                        
                                            
                                         - 
                                        19607-21-7
                                        
methyl 3,3,3-trifluoro-2-hydroxy-2-methoxypropanoate
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuric acid; silica gel; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 125 ℃;
                                                            
                                                            for 0.5h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        94.5% | 
                                
- 
                                        
                                            
                                         - 
                                        10186-63-7
                                        
2-fluoro-2-methoxy trifluoropropanoic acid methyl ester
 
                                - 
                                        
                                            
                                         - 
                                        431-47-0
                                        
trifluoroacetic acid-methyl ester
 
                                - 
                                        
                                            
                                         - 
                                        13089-11-7
                                        
methyl 3,3,3-trifluoropyruvate
 
                                - 
                                        
                                            
                                         - 
                                        19390-75-1
                                        
methyl 3,3,3-trifluoro-2,2-dihydroxypropanoate
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuric acid; silica gel; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 140 ℃;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        12% 14% 46%  | 
                                
13089-11-7 Upstream products
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                                10186-63-7
                                2-fluoro-2-methoxy trifluoropropanoic acid methyl ester
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                                67-56-1
                                methanol
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                                428-59-1
                                Hexafluoropropene oxide
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                                123202-05-1
                                Sodium; 2,3,3,3-tetrafluoro-2-methoxy-propionate
 
13089-11-7 Downstream products
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                                126956-18-1
                                N-methyl-2-(1-methoxycarbonyl-1-hydroxy-2,2,2-trifluoroethyl)pyrrole
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                                132145-24-5
                                methyl 2-benzoylimino-3,3,3-trifluoropropionate
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                                136308-19-5
                                4-Cyclohexylidene-2-hydroxy-2-trifluoromethyl-butyric acid methyl ester
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                                117015-45-9
                                methyl ester of 2-hydroxy-2-trifluoromethyl-4-pentenoic acid
 
 
 