Pharmaceutial Intermediates
  • Dibenzofuran, 1-nitro-

    • Product Name   :   

      Dibenzofuran, 1-nitro-

    • CAS No   :   

      87812-99-5

    • Project State   :   

      Commercial

    Application

    General Description

    Cost-effective and customizable Dibenzofuran, 1-nitro- 87812-99-5 factory

    • Molecular Formula:C12H7NO3
    • Molecular Weight:213.192
    • Vapor Pressure:1.26E-05mmHg at 25°C 
    • Boiling Point:379.6°C at 760 mmHg 
    • Flash Point:183.4°C 
    • PSA:58.96000 
    • Density:1.399g/cm3 
    • LogP:4.01740 

    87812-99-5 Relevant articles

    Tetramethylammonium fluoride tetrahydrate-mediated transition metal-free coupling of aryl iodides with unactivated arenes in air

    Nozawa-Kumada, Kanako,Nakamura, Kosuke,Kurosu, Satoshi,Iwakawa, Yuki,Denneval, Charline,Shigeno, Masanori,Kondo, Yoshinori

    , p. 1042 - 1045 (2019/10/02)

    Biaryls are important compounds with wid...

    An aromatic heterocyclic compound and use thereof

    -

    Paragraph 0231; 0234-0237, (2019/11/04)

    The invention provides an aromatic heter...

    Preparation method of 1-iododibenzofuran

    -

    Paragraph 0022-0024; 0027-0029, (2019/08/03)

    The invention provides a preparation met...

    PHOSPHORESCENT EMITTERS

    -

    , (2011/09/16)

    Compounds including a ligand with a dibe...

    87812-99-5 Process route

    1-nitro-3-phenoxybenzene
    620-55-3

    1-nitro-3-phenoxybenzene

    3-nitrodibenzofuran
    5410-97-9

    3-nitrodibenzofuran

    1-nitrodibenzofuran
    87812-99-5

    1-nitrodibenzofuran

    Conditions
    Conditions Yield
    With palladium diacetate; In trifluoroacetic acid; at 70 ℃; for 1h;
    44%
    dibenzofuran
    132-64-9,214827-48-2

    dibenzofuran

    3-nitrodibenzofuran
    5410-97-9

    3-nitrodibenzofuran

    2-nitrodibenzofuran
    20927-95-1

    2-nitrodibenzofuran

    4-nitrodibenzo[b,d]furan
    86607-81-0

    4-nitrodibenzo[b,d]furan

    1-nitrodibenzofuran
    87812-99-5

    1-nitrodibenzofuran

    Conditions
    Conditions Yield
    With tetranitromethane; In trifluoroacetic acid; at 0 ℃; for 10h; Product distribution; Mechanism; Irradiation; -45 deg. C, also in dark; regioselectivity studied;
    6%
    11%
    83%
    1%
    With nitric acid; trifluoroacetic acid; at 0 ℃; for 0.5h;
    80%
    With aluminium trichloride; ethyl nitrate; In nitromethane; at 25 ℃; for 1h; Further byproducts given;
    17%
    5%
    28%
    With tetranitromethane; In trifluoroacetic acid; at 0 ℃; for 10h; Product distribution; Mechanism; Irradiation; positional reactivity of dibenzofuran; charge-transfer nitration; other solvents;
    6 % Chromat.
    11 % Chromat.
    83 % Chromat.
    1 % Chromat.
    With sodium azide; sulfuric acid; sodium nitrite; In acetic acid; at 20 ℃; for 20h; Product distribution; var. reagents, solvents, temp.;

    87812-99-5 Upstream products

    • 132-64-9
      132-64-9

      dibenzofuran

    • 99-65-0
      99-65-0

      meta-dinitrobenzene

    • 533-58-4
      533-58-4

      2-Iodophenol

    • 104-82-5
      104-82-5

      4-Methylbenzyl chloride

    87812-99-5 Downstream products

    • 1332882-07-1
      1332882-07-1

      1-(2,4-diisopropyldibenzo[b,d]furan-1-yl)-2-phenyl-1H-imidazole

    • 50548-40-8
      50548-40-8

      1-aminodibenzofuran

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