Pharmaceutial Intermediates
  • 9-Fluorenemethanol

    • Product Name   :   

      9-Fluorenemethanol

    • CAS No   :   

      24324-17-2

    • Project State   :   

      Commercial

    Application

    General Description

    Cost-effective and customizable 9-Fluorenemethanol 24324-17-2 in stock

    • Molecular Formula:C14H12O
    • Molecular Weight:196.249
    • Appearance/Colour:white to pale yellow crystalline powder 
    • Vapor Pressure:6.2E-06mmHg at 25°C 
    • Melting Point:105-107 °C(lit.) 
    • Refractive Index:1.638 
    • Boiling Point:363.9 °C at 760 mmHg 
    • PKA:13.68±0.10(Predicted) 
    • Flash Point:167.4 °C 
    • PSA:20.23000 
    • Density:1.175 g/cm3 
    • LogP:2.79120 

    9-Fluorenemethanol(Cas 24324-17-2) Usage

    General Description

    Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.

    InChI:InChI=1/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2

    24324-17-2 Relevant articles

    Formation and verification of the structure of the 1-fluorenylmethyl chloroformative derivative of sulfamethazine

    Liang,Zhang,Baker,Cross

    , p. 86 - 92 (1996)

    Sulfamethazine (SMZ) is derivatized with...

    Application of the Curtius rearrangement to the synthesis of 1′-aminoferrocene-1-carboxylic acid derivatives

    Erb, William,Levanen, Gael,Roisnel, Thierry,Dorcet, Vincent

    , p. 3808 - 3818 (2018)

    The shortest synthesis of N-protected 1′...

    -

    Brown,Bluestein

    , (1943)

    -

    SAR of novel biarylmethylamine dopamine D4 receptor ligands

    Arlt, Michael,Boettcher, Henning,Riethmueller, Angelika,Schneider, Guenter,Bartoszyk, Gerd D.,Greiner, Hartmut,Seyfried, Christoph A.

    , p. 2033 - 2038 (1998)

    SAR for a novel series of dopamine D4 re...

    Me3SI-promoted chemoselective deacetylation: a general and mild protocol

    Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj

    , p. 19310 - 19315 (2021/06/03)

    A Me3SI-mediated simple and efficient pr...

    Method for high-selectivity synthesis of 9-fluorenylcarbinol

    -

    Paragraph 0025-0080, (2021/06/06)

    The invention discloses a method for hig...

    Preparation method of 9-hydroxymethyl-fluorene diacid

    -

    Paragraph 0039-0045; 0062-0063; 0068-0069; 0074-0075, (2020/12/10)

    The invention provides a method for prep...

    KMnO4-catalyzed chemoselective deprotection of acetate and controllable deacetylation-oxidation in one pot

    Gurawa, Aakanksha,Kumar, Manoj,Rao, Dodla S.,Kashyap, Sudhir

    supporting information, p. 16702 - 16707 (2020/10/27)

    A novel and efficient protocol for chemo...

    24324-17-2 Process route

    (9H-fluoren-9-ylmethoxy)trimethylsilane
    1162648-59-0

    (9H-fluoren-9-ylmethoxy)trimethylsilane

    9-Fluorenylmethanol
    24324-17-2

    9-Fluorenylmethanol

    Conditions
    Conditions Yield
    With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate; at 20 ℃; for 0.0833333h; Green chemistry;
    99%
    With rice husk ash supported on anatase-phase titania nanoparticles nanocomposite; In methanol; at 20 ℃; for 0.05h;
    94%
    With methanol; vanadium hydrogen sulfate; at 20 ℃; for 0.0833333h;
    92%
    With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite; In methanol; at 20 ℃; for 0.133333h;
    91%
    With methanol; at 20 ℃; for 0.0833333h;
    85%
    formaldehyd
    50-00-0,30525-89-4,61233-19-0

    formaldehyd

    9H-fluorene
    86-73-7

    9H-fluorene

    9-Fluorenylmethanol
    24324-17-2

    9-Fluorenylmethanol

    Conditions
    Conditions Yield
    9H-fluorene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃;
    formaldehyd; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 5h;
    71%
    9H-fluorene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.133333h;
    formaldehyd; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1.5h;
    30.5%
    With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dimethyl sulfoxide; at 20 ℃; for 0.333333h; Solvent;
    17%
    With N-benzyl-trimethylammonium hydroxide; In pyridine;

    24324-17-2 Upstream products

    • 67-56-1
      67-56-1

      methanol

    • 832-80-4
      832-80-4

      9-diazofluorenone

    • 50-00-0
      50-00-0

      formaldehyd

    • 86-73-7
      86-73-7

      9H-fluorene

    24324-17-2 Downstream products

    • 85-01-8
      85-01-8

      phenanthrene

    • 85055-70-5
      85055-70-5

      (9H-fluoren-9-yl)methyl benzoate

    • 71532-40-6
      71532-40-6

      (9H-fluoren-9-yl)methyl 4-methylbenzenesulfonaye

    • 28920-43-6
      28920-43-6

      (fluorenylmethoxy)carbonyl chloride

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