9-Fluorenemethanol
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Product Name :
9-Fluorenemethanol
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CAS No :
24324-17-2
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Project State :
Commercial
 
            Application
General Description
Cost-effective and customizable 9-Fluorenemethanol 24324-17-2 in stock
- Molecular Formula:C14H12O
 - Molecular Weight:196.249
 - Appearance/Colour:white to pale yellow crystalline powder
 - Vapor Pressure:6.2E-06mmHg at 25°C
 - Melting Point:105-107 °C(lit.)
 - Refractive Index:1.638
 - Boiling Point:363.9 °C at 760 mmHg
 - PKA:13.68±0.10(Predicted)
 - Flash Point:167.4 °C
 - PSA:20.23000
 - Density:1.175 g/cm3
 - LogP:2.79120
 
9-Fluorenemethanol(Cas 24324-17-2) Usage
| 
                             General Description  | 
             			Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.  | 
             		
InChI:InChI=1/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2
24324-17-2 Relevant articles
Formation and verification of the structure of the 1-fluorenylmethyl chloroformative derivative of sulfamethazine
Liang,Zhang,Baker,Cross
, p. 86 - 92 (1996)
Sulfamethazine (SMZ) is derivatized with...
Application of the Curtius rearrangement to the synthesis of 1′-aminoferrocene-1-carboxylic acid derivatives
Erb, William,Levanen, Gael,Roisnel, Thierry,Dorcet, Vincent
, p. 3808 - 3818 (2018)
The shortest synthesis of N-protected 1′...
-
Brown,Bluestein
, (1943)
-
SAR of novel biarylmethylamine dopamine D4 receptor ligands
Arlt, Michael,Boettcher, Henning,Riethmueller, Angelika,Schneider, Guenter,Bartoszyk, Gerd D.,Greiner, Hartmut,Seyfried, Christoph A.
, p. 2033 - 2038 (1998)
SAR for a novel series of dopamine D4 re...
Me3SI-promoted chemoselective deacetylation: a general and mild protocol
Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj
, p. 19310 - 19315 (2021/06/03)
A Me3SI-mediated simple and efficient pr...
Method for high-selectivity synthesis of 9-fluorenylcarbinol
-
Paragraph 0025-0080, (2021/06/06)
The invention discloses a method for hig...
Preparation method of 9-hydroxymethyl-fluorene diacid
-
Paragraph 0039-0045; 0062-0063; 0068-0069; 0074-0075, (2020/12/10)
The invention provides a method for prep...
KMnO4-catalyzed chemoselective deprotection of acetate and controllable deacetylation-oxidation in one pot
Gurawa, Aakanksha,Kumar, Manoj,Rao, Dodla S.,Kashyap, Sudhir
supporting information, p. 16702 - 16707 (2020/10/27)
A novel and efficient protocol for chemo...
24324-17-2 Process route
- 
                                        
                                            
                                         - 
                                        1162648-59-0
                                        
(9H-fluoren-9-ylmethoxy)trimethylsilane
 
                                - 
                                        
                                            
                                         - 
                                        24324-17-2
                                        
9-Fluorenylmethanol
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.0833333h;
                                                            
                                                Green chemistry;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        99% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    rice husk ash supported on anatase-phase titania nanoparticles nanocomposite; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                methanol; 
                                            
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.05h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        94% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    methanol; vanadium hydrogen sulfate; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.0833333h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        92% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                methanol; 
                                            
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.133333h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        91% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    methanol; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.0833333h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        85% | 
                                
- 
                                        
                                            
                                         - 
                                        50-00-0,30525-89-4,61233-19-0
                                        
formaldehyd
 
                                - 
                                        
                                            
                                         - 
                                        86-73-7
                                        
9H-fluorene
 
                                - 
                                        
                                            
                                         - 
                                        24324-17-2
                                        
9-Fluorenylmethanol
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                9H-fluorene; 
                                            
                                            With 
                                            
                                            
                                                
                                                    n-butyllithium; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrahydrofuran; hexane; 
                                            
                                            
                                            
                                                
                                                            at 0 ℃;
                                                            
                                            
                                         
                                        
                                        
                                            
                                                formaldehyd; 
                                            
                                            
                                                
                                                    
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrahydrofuran; hexane; 
                                            
                                            
                                            
                                                
                                                            at 0 - 20 ℃;
                                                            
                                                            for 5h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        71% | 
                                
| 
                                        
                                         
                                            
                                                9H-fluorene; 
                                            
                                            With 
                                            
                                            
                                                
                                                    n-butyllithium; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrahydrofuran; hexane; 
                                            
                                            
                                            
                                                
                                                            at 0 ℃;
                                                            
                                                            for 0.133333h;
                                                            
                                            
                                         
                                        
                                        
                                            
                                                formaldehyd; 
                                            
                                            
                                                
                                                    
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                tetrahydrofuran; hexane; 
                                            
                                            
                                            
                                                
                                                            at 0 - 20 ℃;
                                                            
                                                            for 1.5h;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        30.5% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    1,8-diazabicyclo[5.4.0]undec-7-ene; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                dimethyl sulfoxide; 
                                            
                                            
                                            
                                                
                                                            at 20 ℃;
                                                            
                                                            for 0.333333h;
                                                            
                                                Solvent;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        17% | 
                                
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    N-benzyl-trimethylammonium hydroxide; 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                pyridine; 
                                            
                                            
                                            
                                                
                                            
                                         
                                        
                                     | 
                                    
24324-17-2 Upstream products
- 
                           
                                67-56-1
                                methanol
 - 
                           
                                832-80-4
                                9-diazofluorenone
 - 
                           
                                50-00-0
                                formaldehyd
 - 
                           
                                86-73-7
                                9H-fluorene
 
24324-17-2 Downstream products
- 
                            
                                85-01-8
                                phenanthrene
 - 
                            
                                85055-70-5
                                (9H-fluoren-9-yl)methyl benzoate
 - 
                            
                                71532-40-6
                                (9H-fluoren-9-yl)methyl 4-methylbenzenesulfonaye
 - 
                            
                                28920-43-6
                                (fluorenylmethoxy)carbonyl chloride
 
 
 