Acetylacetaldehyde dimethyl acetal
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Product Name :
Acetylacetaldehyde dimethyl acetal
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CAS No :
5436-21-5
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Project State :
Commercial
 
            Application
General Description
High quality purity >99% Acetylacetaldehyde dimethyl acetal 5436-21-5 for sale
- Molecular Formula:C6H12O3
 - Molecular Weight:132.159
 - Appearance/Colour:Clear colorless to yellow liquid
 - Vapor Pressure:1.35mmHg at 25°C
 - Melting Point:-82 °C
 - Refractive Index:n20/D 1.414(lit.)
 - Boiling Point:172.1 °C at 760 mmHg
 - Flash Point:49.4 °C
 - PSA:35.53000
 - Density:0.959 g/cm3
 - LogP:0.58440
 
Acetylacetaldehyde dimethyl acetal(Cas 5436-21-5) Usage
| 
                             Synthesis Reference(s)  | 
             			The Journal of Organic Chemistry, 41, p. 3765, 1976 DOI: 10.1021/jo00885a028Tetrahedron Letters, 28, p. 6657, 1987 DOI: 10.1016/S0040-4039(00)96938-7  | 
             		
| 
                             General Description  | 
             			4,4-Dimethoxy-2-butanone (Acetylacetaldehyde dimethylacetal) is a ketone.  | 
             		
InChI:InChI=1/C6H12O3/c1-5(7)4-6(8-2)9-3/h6H,4H2,1-3H3
5436-21-5 Relevant articles
Biosynthesis of polyketide-terpenoid (Meroterpenoid) metabolites andibenin B and andilesin A in aspergillus variecolor
Simpson, Thomas J.,Anmed, Salman A.,McIntyre, C. Rupert,Scott, Fiona E.,Sadler, Ian H.
, p. 4013 - 4034 (1997)
Incorporation of 13C-labelled acetates a...
Synthesis method of 4,4-dimethoxy-2-butanone
-
Paragraph 0017-0037, (2021/11/06)
The invention discloses a synthesis meth...
Electronic Asymmetry of an Annelated Pyridyl-Mesoionic Carbene Scaffold: Application in Pd(II)-Catalyzed Wacker-Type Oxidation of Olefins
Bera, Jitendra K.,Dutta, Indranil,Kunnikuruvan, Sooraj,Reshi, Noor U Din,Saha, Sayantani,Yadav, Suman
, p. 11385 - 11393 (2020/11/23)
The two donor modules of an annelated py...
CuII-Catalyzed Oxidative Formation of 5-Alkynyltriazoles
Liu, Peiye,Brassard, Christopher J.,Lee, Justin P.,Zhu, Lei
supporting information, p. 380 - 390 (2020/01/24)
In an alcoholic solvent under the cataly...
New process for preparing pyrazole carboxylic acid derivatives
-
Paragraph 0047; 0065-0070, (2017/04/03)
The present invention relates to a metho...
5436-21-5 Process route
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                                         - 
                                        72380-56-4
                                        
3-butenal dimethyl acetal
 
                                - 
                                        
                                            
                                         - 
                                        5436-21-5
                                        
acetylacetaldehyde dimethyl acetal
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-); 
                                            
                                            
                                                
                                            
                                            In 
                                            
                                                decane; acetonitrile; 
                                            
                                            
                                            
                                                
                                                            at 70 ℃;
                                                            
                                                            for 24h;
                                                            
                                                Temperature;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        95% | 
                                
- 
                                        
                                            
                                         - 
                                        124-41-4
                                        
sodium methylate
 
                                - 
                                        
                                            
                                         - 
                                        67-64-1
                                        
acetone
 
                                - 
                                        
                                            
                                         - 
                                        109-94-4
                                        
formic acid ethyl ester
 
                                - 
                                        
                                            
                                         - 
                                        5436-21-5
                                        
acetylacetaldehyde dimethyl acetal
 
| Conditions | Yield | 
|---|---|
| 
                                        
                                         
                                            
                                                
                                            
                                            With 
                                            
                                            
                                                
                                                    sulfuric acid; 
                                            
                                            
                                                
                                            
                                            
                                                
                                                            at 0 - 50 ℃;
                                                            
                                                            for 2h;
                                                            
                                                Temperature;
                                                            
                                            
                                         
                                        
                                     | 
                                    
                                        73.2% | 
                                
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- 
                           
                                67-56-1
                                methanol
 - 
                           
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                                1-methoxy-buten-3-yne
 - 
                           
                                56-23-5
                                tetrachloromethane
 - 
                           
                                7119-27-9
                                4-chloro-3-buten-2-one
 
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