Pesticide Intermediates
  • 3-Pyridinecarboxaldehyde

    • Product Name   :   

      3-Pyridinecarboxaldehyde

    • CAS No   :   

      500-22-1

    • Project State   :   

      Commercial

    General Description

    Cost-effective and customizable 3-Pyridinecarboxaldehyde 500-22-1 in stock

    • Molecular Formula:C6H5NO
    • Molecular Weight:107.112
    • Appearance/Colour:clear brown-yellow liquid (clear) 
    • Vapor Pressure:0.198mmHg at 25°C 
    • Melting Point:8 °C 
    • Refractive Index:n20/D 1.549(lit.)  
    • Boiling Point:209.9 °C at 760 mmHg 
    • PKA:3.43±0.10(Predicted) 
    • Flash Point:60 °C 
    • PSA:29.96000 
    • Density:1.135 g/cm3 
    • LogP:0.89410 

    3-Pyridinecarboxaldehyde(Cas 500-22-1) Usage

    Synthesis Reference(s)

    Synthetic Communications, 21, p. 1777, 1991 DOI: 10.1080/00397919108021576Tetrahedron, 32, p. 2549, 1976 DOI: 10.1016/0040-4020(76)88025-8Tetrahedron Letters, 35, p. 8019, 1994 DOI: 10.1016/0040-4039(94)80038-3

    Purification Methods

    Purified as for pyridine-2-aldehyde. [Beilstein 21 I 288, 21 III/IV 3517, 21/7 V 334.]

    Definition

    ChEBI: A pyridinecarbaldehyde that is pyridine substituted by a formyl group at position 3.

    InChI:InChI=1/C6H5NO/c8-5-6-2-1-3-7-4-6/h1-5H

    500-22-1 Relevant articles

    -

    Suvorov et al.

    , (1969)

    -

    V2O5/TiO2 Catalysts for the Vapor-Phase Oxidation of β-Picoline: Influence of the TiO2-Carrier

    Heinz,Hoelderich,Krill,Boeck,Huthmacher

    , p. 1 - 10 (2000)

    The heterogeneously catalyzed vapor-phas...

    Selective photocatalytic oxidation of 3-pyridinemethanol on platinized acid/base modified TiO2

    ?etinkaya, S?d?ka,Augugliaro, Vincenzo,Garlisi, Corrado,Lewin, Erik,Palmisano, Giovanni,Sá, Jacinto,Yurdakal, Sedat

    , p. 4549 - 4559 (2021)

    TiO2catalysts, modified with acidic or a...

    Degradation of quinoline by wet oxidation - Kinetic aspects and reaction mechanisms

    Thomsen, Anne Belinda

    , p. 136 - 146 (1998)

    The high temperature, high pressure wet ...

    Mild reductive deoximation with TiCl4/NaI reagent system

    Balicki,Kaczmarek

    , p. 1777 - 1782 (1991)

    The application of the TiCl4/NaI reagent...

    3-picoline oxidation over monoclinic orthovanadate Cr0.5Al0.5VO4 catalysts

    Zhaoxia, Song,Kadowaki, Eriko,Shishido, Tetsuya,Wang, Ye,Takehira, Katsuomi

    , p. 754 - 755 (2001)

    Monoclinic orthovanadate CrVO4-I was fou...

    -

    Schoenberg,A.,Heck,R.F.

    , p. 7761 - 7764 (1974)

    -

    TiO2/graphene-like photocatalysts for selective oxidation of 3-pyridine-methanol to vitamin B3 under UV/solar simulated radiation in aqueous solution at room conditions: The effect of morphology on catalyst performances

    Alfè, Michela,Spasiano, Danilo,Gargiulo, Valentina,Vitiello, Giuseppe,Capua, Roberto Di,Marotta, Raffaele

    , p. 91 - 99 (2014)

    Graphene-like layers, synthesized throug...

    Micellar effects on kinetics and mechanism of Vilsmeier–Haack formylation and acetylation with Pyridines

    Alyami, Bandar A.,Iqubal, S. M. Shakeel,Khan, Aejaz Abdullatif,Mohammed, Tasneem

    , (2022/01/19)

    An efficient preparation of Vilsmeier–Ha...

    Photoredox-Catalyzed Simultaneous Olefin Hydrogenation and Alcohol Oxidation over Crystalline Porous Polymeric Carbon Nitride

    Qiu, Chuntian,Sun, Yangyang,Xu, Yangsen,Zhang, Bing,Zhang, Xu,Yu, Lei,Su, Chenliang

    , p. 3344 - 3350 (2021/07/26)

    Booming of photocatalytic water splittin...

    Preparation of tungstophosphoric acid/cerium-doped NH2-UiO-66 Z-scheme photocatalyst: a new candidate for green photo-oxidation of dibenzothiophene and quinoline using molecular oxygen as the oxidant

    Fakhri, Hanieh,Esrafili, Ali,Farzadkia, Mahdi,Boukherroub, Rabah,Srivastava, Varsha,Sillanp??, Mika

    , p. 10897 - 10906 (2021/06/27)

    The goal of this study was to introduce ...

    500-22-1 Process route

    3-hydroxymethylpyridin
    100-55-0

    3-hydroxymethylpyridin

    3-pyridinecarboxaldehyde
    500-22-1

    3-pyridinecarboxaldehyde

    pyridine-3-carbonitrile
    100-54-9,121697-66-3,1232169-17-3,68271-95-4

    pyridine-3-carbonitrile

    Conditions
    Conditions Yield
    With ammonia; oxygen; In tetrahydrofuran; at 120 ℃; for 6h; under 4560.31 Torr;
    3-Methylpyridine
    108-99-6

    3-Methylpyridine

    pyridine
    110-86-1

    pyridine

    3-pyridinecarboxaldehyde
    500-22-1

    3-pyridinecarboxaldehyde

    pyridine-3-carbonitrile
    100-54-9,121697-66-3,1232169-17-3,68271-95-4

    pyridine-3-carbonitrile

    nicotinic acid
    59-67-6

    nicotinic acid

    Conditions
    Conditions Yield
    With vanadia-titania catalyst; at 250 ℃; under 760.051 Torr; Reagent/catalyst; Mechanism; Gas phase; Flow reactor;

    500-22-1 Upstream products

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      N,N-dimethylnicotinamide

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      19182-29-7

      3-formyl-pyridine-2-carboxylic acid

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